COLLOQUIUM
You are invited to attend a lecture by
Professor Sir Richard
Friend, FRS
Optoelectronics Group,
Cavendish Laboratory
University of Cambridge
On:
Organic Semiconductor Devices: Charge
injection, Transport, Recombination and Photoinduced Separation
I will report on several recent advances in the design and operation of organic
semiconductor diodes:
Charge injection has traditionally been achieved with the use of metallic
electrodes, but metal oxides are now known to provide excellent alternatives,
providing ohmic injection of both electrons and holes. I will show that this
provides interesting opportunities to redesign the architecture of
light-emitting diodes.
Charge separation in organic solar cells requires the use of a heterojunction
between two organic semiconductors that can be used to overcome the onsite
Coulomb binding between electron and hole, but the formation of bound
charge-transfer excitations across the heterojunction can limit the efficiency
of simple heterojunction structures. These CT states can evolve to form
spin-triplet excitons that then prevent long-time charge separation. The
magnetic field dependence of the photoluminescence and photoconductivity
provides information about these processes.
The possibility that a spin singlet exciton can split to form two triplet
excitons when the exchange energy is large has been known for many years.
However, the possible use of this process to improve efficiency for solar cells
has now been appreciated. We have carried out transient optical absorption
measurements that reveal that his process is present in pentacene/fullerene solar
cells.
The lecture will take place
On Wednesday, 15/09/2010 at 12:30
in Room 1003 Electrical
Eng. Building
Technion City